Laws were enacted to force heavy polluters, particularly electrical power generation plants burning coal or oil, to put scrubbers in their stacks to remove most of the pollution and fly-ash going up the stack. It’s a pretty decent success story, but one that too many Americans have forgotten The new right wants to get rid of the EPA and go back to pollution as usual. They seem to have forgotten that large swaths of forests and grasslands were dying off in the 70s, and that we actually had rivers catching on fire.
Acid rain does dissolve limestone, and as the acidic runoff gets into the waterwys, lakes and seas, it damages marine life as well. Acids escaping from volcanoes can definitely eat up limestone if there is sufficient dampness in the environment, but this is a naturla process that the Earth easily absorbs and compensates for. Human activity is a much larger concern.