It looks like podcasts only go back as far as September 19. These can be viewed in a list that you can quickly scroll through, either on the CBC site or via iTunes.
You can reach some older episodes using the link that you provided, by clicking the arrows to move back page by page. I was able to access the earliest entry this way, which is from June 23. I also tried entering the number of the last page (34) and the penultimate page (33), and the page hung both times, so that doesn’t appear to work – that might just be me, though. You might have more success.
I’m finding this quite shocking. CBC used to host years of Q episodes. It’s not about Ghomeshi’s fall from grace, either, since they clearly have episodes that he hosted. I can’t imagine why they’d suddenly make older content inaccessible.
Now, if you do a search for a specific artist from the page that you linked, you’ll find that the content is probably all still on the CBC site, somewhere. For example, if you search for “Joni Mitchell” or “Stephen King”, you’ll turn up interviews on Q from years ago. But oddly, a search for “Billy Bob Thornton” (that classic, bizarre interview) turns up nothing – that’s odd.
Anyway, CBC’s website has always been a bit awful for searching for old content, so this doesn’t surprise me too much – but the Q interviews always used to be easy to scroll through by date, so I’m disappointed that they’ve apparently changed how they present this content.
I hope some of this is helpful.