You do not mention your medium or what techniques you have tried so I will
give a general answer which may help.
While it is true that the beauty is impossible to truly capture on canvas there may be
some basic steps blocking you from the best recreation possible.
Painting light is as dependent on you pigments as it is your skill.
To achieve light you need to use pure pigments rather than hues. Pure pigments are the colors milled from the natural source. They are more expensive
because they require only the source from which they were traditionally derived.
Hues are less expensive- Most student and much mid-grade paint are hues. They look the same as the pure pigments on palette however they are created by mixing different colors from different sources and will usually react much differently when mixing and will easily muddy.
I would venture a guess that even the best painter could not capture the incredible glory and light of Italy with hues.
Also be sure you are using a solvent that does not cause pigments to cloud. Read the label- you may be surprised.
Since I am not there with you and do not know what you have already tried nor the vista that you are actually trying to capture it is hard to suggest techniques. I wish I was!
I sometimes use a ground of lead white which I let dry then use transparent pigments to glaze in color when looking to paint light however others have different techniques.