No, you can’t as far as i remember from an earlier, similar question.
What you could do, when that user is commenting on your question and the answer is in any way not in accordance with the guidelines, is flag it, and hope for the best (response being modded away).
Or, when you see the obnoxious user’s avatar, close your eyes and use your mouse wheel to scroll the page twenty centimeters down and you can open your eyes again now.